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Objective-C is the primary language used to write Mac software. If you’re comfortable with basic object-oriented concepts and the C language, Objective-C will make a lot of sense. If you don’t know C, you should read the C Tutorial first. This tutorial is written and illustrated by Scott Stevenson
Cocoa Dev Central: Learn Objective-C & why not? I nicely laid out and style introduction to the Objective-C language (iPhone and Mac OS X)